Proceedings of the Chemical Society Volume 15 download torrent
Proceedings of the Chemical Society Volume 15 download torrent
Proceedings of the Chemical Society Volume 15.cChemical Society
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Author: Chemical Society
Number of Pages: 106 pages
Published Date: 01 May 2012
Publisher: Rarebooksclub.com
Publication Country: Miami Fl, United States
Language: Englishhttps://d1w7fb2mkkr3kw.cloudfront.net/assets/images/book/large/9781/1309/9781130923339.jpg
ISBN: 9781236165305
File Name: Proceedings.of.the.Chemical.Society.Volume.15.pdf
Download Link: Proceedings of the Chemical Society Volume 15
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This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1900 Excerpt: ...CN-CH2-CH(PrP)-CH2-CO2Et, a mobile liquid boiling at 234. The neutral ethylic salt on hydrolysis with methyl alcoholic potash, yields a solid potassium salt, which, on boiling a short time with concentrated hydrochloric acid, becomes the imide, (PrCHQQQNH, a solid substance crystallising from water in lustrous plates melting at 120, and which is quantitatively converted into /3-isopropylglutaric acid on boiling for two hours with a 50 per cent, solution of sulphuric acid. jS-Isopropylglutaric acid, HO2C-CH2-CH(PrP)-CH2-CO2H, prepared either in this way or by the direct hydrolysis of the hydrogen ethylic salt with sulphuric acid, crystallises from water in needles melting at 100, and on treatment with acetyl chloride yields a liquid anhydride boiling at 171 (30 mm.), and an anilic acid crystallising from dilute alcohol in plates melting at 121. This acid does not appear to be identical with that obtained by Angeli and Rimini (Gazz. Chim., 26, 36) from isocamphor on oxidation with potassium permanganate, which melts at 96 and gives an anhydride melting at 60, further the dissociation constant K 0'0646 of the authors' acid, as found by Mr. Lidbury, does not agree with K 0 0052 of Angeli and Rimini's acid. 56. "The synthesis and preparation of terebic and terpenylic acids." By W. Trevor Lawrence. The tertiary hydrogen atom in monobasic aliphatic acids is readily oxidised by potassium permanganate (R. Meyer and Pittig). The author has applied this method to the synthesis of terebic and terpenylic acids. /3-Isopropylglutaric acid is readily oxidised by chromic acid mixture, with the formation of terpenylic acid, confirming Wallach's formula for this acid, namely, Hcbtch-ch c6' The svnthetic acid is identical with the acid obtained by oxidation of oil of...
Read online Proceedings of the Chemical Society Volume 15 Buy and read online Proceedings of the Chemical Society Volume 15 Download Proceedings of the Chemical Society Volume 15 ebook, pdf, djvu, epub, mobi, fb2, zip, rar, torrent Download to iPad/iPhone/iOS, B&N nook Proceedings of the Chemical Society Volume 15 ebook, pdf, djvu, epub, mobi, fb2, zip, rar, torrent
Proceedings of the Chemical Society Volume 15.cChemical Society
Author: Chemical Society
Number of Pages: 106 pages
Published Date: 01 May 2012
Publisher: Rarebooksclub.com
Publication Country: Miami Fl, United States
Language: Englishhttps://d1w7fb2mkkr3kw.cloudfront.net/assets/images/book/large/9781/1309/9781130923339.jpg
ISBN: 9781236165305
File Name: Proceedings.of.the.Chemical.Society.Volume.15.pdf
Download Link: Proceedings of the Chemical Society Volume 15
---------------------------------------------------------------
This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1900 Excerpt: ...CN-CH2-CH(PrP)-CH2-CO2Et, a mobile liquid boiling at 234. The neutral ethylic salt on hydrolysis with methyl alcoholic potash, yields a solid potassium salt, which, on boiling a short time with concentrated hydrochloric acid, becomes the imide, (PrCHQQQNH, a solid substance crystallising from water in lustrous plates melting at 120, and which is quantitatively converted into /3-isopropylglutaric acid on boiling for two hours with a 50 per cent, solution of sulphuric acid. jS-Isopropylglutaric acid, HO2C-CH2-CH(PrP)-CH2-CO2H, prepared either in this way or by the direct hydrolysis of the hydrogen ethylic salt with sulphuric acid, crystallises from water in needles melting at 100, and on treatment with acetyl chloride yields a liquid anhydride boiling at 171 (30 mm.), and an anilic acid crystallising from dilute alcohol in plates melting at 121. This acid does not appear to be identical with that obtained by Angeli and Rimini (Gazz. Chim., 26, 36) from isocamphor on oxidation with potassium permanganate, which melts at 96 and gives an anhydride melting at 60, further the dissociation constant K 0'0646 of the authors' acid, as found by Mr. Lidbury, does not agree with K 0 0052 of Angeli and Rimini's acid. 56. "The synthesis and preparation of terebic and terpenylic acids." By W. Trevor Lawrence. The tertiary hydrogen atom in monobasic aliphatic acids is readily oxidised by potassium permanganate (R. Meyer and Pittig). The author has applied this method to the synthesis of terebic and terpenylic acids. /3-Isopropylglutaric acid is readily oxidised by chromic acid mixture, with the formation of terpenylic acid, confirming Wallach's formula for this acid, namely, Hcbtch-ch c6' The svnthetic acid is identical with the acid obtained by oxidation of oil of...
Read online Proceedings of the Chemical Society Volume 15 Buy and read online Proceedings of the Chemical Society Volume 15 Download Proceedings of the Chemical Society Volume 15 ebook, pdf, djvu, epub, mobi, fb2, zip, rar, torrent Download to iPad/iPhone/iOS, B&N nook Proceedings of the Chemical Society Volume 15 ebook, pdf, djvu, epub, mobi, fb2, zip, rar, torrent